SOLVATION DYNAMICS IN ELECTROLYTE-SOLUTIONS

被引：42

作者：

CHANDRA, A

PATEY, GN

机构：

[1] Department of Chemistry, University of British Columbia, Vancouver

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 02期

关键词：

D O I：

10.1063/1.466634

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A microscopic theory of the dynamics of ion solvation in electrolyte solutions is given. Consistent with the pure solvent case, the theory predicts a very fast and important inertial relaxation at short times. This is followed by oscillations and an extremely slow long-time decay associated with the formation of an equilibrium ''ion atmosphere'' about the newly charged particle.

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页码：1552 / 1558

页数：7

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