REACTIONS OF 1-(PHENYLSULPHONYLMETHYL)BENZOTRIAZOLE WITH SOME NITROARENES

被引：6

作者：

BERNARD, MK

机构：

[1] Department of Organic Chemistry, Medical Academy, 60-780 Poznan

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 12期

关键词：

D O I：

10.1016/0040-4039(95)00204-P

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of nitroarenes 2 - 6 with 1-(phenylsulphonylmethyl)benzotriazole 1 in the KOH - DMSO base-solvent system at room temperature results in cleavage of the phenylsulphonyl group, while the t-BuOK - DMF system at low temperature promotes oxidation of the reaction intermediates.

引用

页码：2169 / 2172

页数：4

共 10 条

[1]

BERNARD MK, 1990, LIEBIGS ANN CHEM, P755

[2]

BERNARD MK, 1989, LIEBIGS ANN CHEM, P545

[3]

KATRITZKY AR, 1994, SYNTHESIS-STUTTGART, P445

[4] THE CHEMISTRY OF N-SUBSTITUTED BENZOTRIAZOLES .1. 1-(CHLOROMETHYL)-BENZOTRIAZOLE [J].