ALPHA-OXIDATION OF KETONES USING N-CATION RADICALS

被引：19

作者：

SCHULZ, M

KLUGE, R

SIVILAI, L

KAMM, B

机构：

[1] Department of Chemistry Technical University Carl Schorlemmer MerseburgGDR

来源：

TETRAHEDRON | 1990年 / 46卷 / 07期

关键词：

D O I：

10.1016/S0040-4020(01)82017-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Six-membered ring ketones and acyclic ketones were oxidized by stable triarylamminium radical cations in moist acetonitrile at room temperature in the presence of a base to α-hydroxy ketones in good yield. Five-membered ring ketones gave the corresponding αβ-unsaturated compounds. © 1990.

引用

页码：2371 / 2380

页数：10

共 36 条

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