Solvent Induced Conformational Kinetics (SICK)

被引：8

作者：

Jonkman, Leffert ^{[1
]}

Kommandeur, Jan ^{[1
]}

机构：

[1] Univ Groningen, Phys Chem Lab, NL-9747 AG Groningen, Netherlands

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 5卷 / 09期

关键词：

D O I：

10.1016/0009-2614(70)85052-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Specific conformations of molecules may be induced by the solvent when a large free volume is associated with the oonformational change. The conformational energy barrier is then a property of the solvent, rather than of the molecule. Such effects are reported for several substituted phenyl-benzyl-nitroxides, where Solvent Induced Conformational Kinetics ( SICK) can be studied by ESR.

引用

页码：579 / 583

页数：5