STEREOSELECTIVE MICHAEL ADDITION-REACTIONS OF ACYLATED OXAZOLIDINONES TO ETHYL 3-TRIFLUOROMETHYLACRYLATE

被引：46

作者：

YAMAZAKI, T ^{[1
]}

HAGA, J ^{[1
]}

KITAZUME, T ^{[1
]}

机构：

[1] TOKYO INST TECHNOL, DEPT BIOENGN, MIDORI KU, YOKOHAMA, KANAGAWA 227, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 12期

关键词：

D O I：

10.1246/cl.1991.2175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Michael addition reactions of acyl oxazolidinones to ethyl 3-trifluoromethylacrylate were found to proceed smoothly with a high degree of diastereo- as well as diastereofacial selectivity at the new carbon-carbon bond.

引用

页码：2175 / 2178

页数：4

共 7 条

[1]

Evans D. A., 1982, ALDRICHIM ACTA, V15, P23

[2] ENANTIOSELECTIVE ALDOL CONDENSATIONS .2. ERYTHRO-SELECTIVE CHIRAL ALOL CONDENSATIONS VIA BORON ENOLATES [J].

EVANS, DA ;

BARTROLI, J ;

SHIH, TL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (08) :2127-2129

[3] CONTRASTERIC CARBOXIMIDE HYDROLYSIS WITH LITHIUM HYDROPEROXIDE [J].

EVANS, DA ;

BRITTON, TC ;

ELLMAN, JA .

TETRAHEDRON LETTERS, 1987, 28 (49) :6141-6144

[4] ASYMMETRIC ALKYLATION REACTIONS OF CHIRAL IMIDE ENOLATES - A PRACTICAL APPROACH TO THE ENANTIOSELECTIVE SYNTHESIS OF ALPHA-SUBSTITUTED CARBOXYLIC-ACID DERIVATIVES [J].

EVANS, DA ;

ENNIS, MD ;

MATHRE, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (06) :1737-1739

[5]

EVANS DA, 1984, ASYMMETRIC SYNTHESIS, V3, P1

[6]

OARE DA, 1989, TOP STEREOCHEM, V19, P227

[7] HIGHLY DIASTEREOSELECTIVE MICHAEL ADDITION-REACTIONS OF LITHIUM ENOLATES TO ETHYL 3-TRIFLUOROMETHYLACRYLATE [J].

YAMAZAKI, T ;

HAGA, J ;

KITAZUME, T ;

NAKAMURA, S .

CHEMISTRY LETTERS, 1991, (12) :2171-2174

← 1 →