THE SYNTHESIS OF MONO-METHYL AND DIMETHYL GALLIUM TETRAAZA MACROCYCLES [MEGA(C22H22N4)] AND [ME2GA(C22H23N4)] AND THE MOLECULAR-STRUCTURE OF THE DIMETHYL GALLIUM DERIVATIVE

被引：8

作者：

ALCOCK, NW

BLACKER, NC

WALLBRIDGE, MGH

BARKER, J

机构：

[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

[2] ASSOCIATED OCTEL CO LTD,WIRRAL L65 4HR,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 419卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)80254-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of gallium trimethyl with the dibenzo-tetra-aza macrocycle, C22H24N4, results in the formation of the dimethyl gallium-macrocycle, [Me2Ga(C22H23N4)]. A single crystal X-ray diffraction study of the complex shows the gallium to be in a near tetrahedral environment and bonded to two of the four nitrogen atoms, with two nearly equal Ga-N distances. The other two nitrogen atoms form an internal hydrogen bond (N...N 2.675(8) angstrom). The compound loses an additional mole of methane above 200-degrees-C and is converted quantitatively into the monomethyl derivative [MeGa(C22H22N4)].

引用

页码：C23 / C26

页数：4

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