CHARACTERIZATION OF STRONGLY BOUND TRANSITION-METAL-MOLECULAR SILANE CATIONIC COMPLEXES IN THE GAS-PHASE

被引：4

作者：

BAKHTIAR, R ^{[1
]}

JACOBSON, DB ^{[1
]}

机构：

[1] N DAKOTA STATE UNIV, DEPT CHEM, FARGO, ND 58105 USA

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 08期

关键词：

D O I：

10.1021/om00032a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Formation and characterization of strongly bound molecular silane-Fe+ complexes are described in the gas phase by using Fourier transform mass spectrometry (FTMS). The relative order of silane binding energieS is Me2SiH2 > Me3SiH > MeSiH3 > Me4Si > SiH4. The binding energy of SiH4 exceeds 31.3 +/- 1.8 kcal/mol, and the binding energy of Me2SiH2 is ca. 39.9 +/- 1.4 kcal/mol.

引用

页码：2876 / 2878

页数：3

共 54 条

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[2]

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