REACTIVITY OF ANIONIC ZIRCONAOXIRANES TOWARD METAL-CARBONYLS - IMPLICATIONS FOR THE MECHANISM OF HOMOGENEOUSLY CATALYZED CARBON-MONOXIDE HYDROGENATION

被引：10

作者：

ASKHAM, FR

CARROLL, KM

BRIGGS, PM

RHEINGOLD, AL

HAGGERTY, BS

机构：

[1] Department of Chemistry and Biochemistry, University of Delaware, Newark

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 06期

关键词：

D O I：

10.1021/om00018a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of anionic zirconocene eta2-aldehyde complexes with metal carbonyls lead to rapid and quantitative formation of heterobimetallic complexes containing a new carbon-carbon bond, thereby suggesting a modified mechanism for homogeneously catalyzed carbon monoxide hydrogenation. Nine new bimetallic complexes are reported, including the X-ray structure of (eta5-C5H4Me)2Zr(Me){OCH(C6H4Me)C(O)Fe(CO)4]Li-(THF)2.

引用

页码：2139 / 2140

页数：2

共 25 条

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