SPECTROSCOPY OF HEXAFLUORIDES WITH AN ODD NUMBER OF ELECTRONS - OPERATORS OF INTEREST FOR ELECTRONIC SPECTROSCOPY AND FOR THE JAHN-TELLER EFFECT

被引：18

作者：

BOUDON, V

MICHELOT, F

MORETBAILLY, J

机构：

[1] Laboratoire de Physique de l'Universität de Bourgogne, Unité Associée an CNRS, Universität de Bourgogne, Dijon

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1994年 / 166卷 / 02期

关键词：

D O I：

10.1006/jmsp.1994.1208

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

A simplified model describing the electronic levels of a (f2g)n configuration is proposed. A new tensorial formulation for Jahn-Teller (linear, quadratic,. . .) operators is developed. Particular attention is given to the case of electronic states with G' symmetry and to their vibronic structures. Calculations and predictions are made for the a and e electronic states of IrF6. (C) 1994 Academic Press, Inc.

引用

页码：449 / 470

页数：22

共 19 条

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