GIF-TYPE OXIDATION SYSTEMS - EVIDENCE FOR A 2ND INTERMEDIATE BETWEEN SATURATED-HYDROCARBON AND KETONE

被引：9

作者：

BARTON, DHR

CSUHAI, E

OZBALIK, N

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 20期

关键词：

D O I：

10.1016/0040-4039(90)80156-G

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of dianisyl telluride to a GifIV oxidation of adamantane has a marked effect on the ratio of ketone to secondary alcohol formed. This is interpreted as an indication of a second intermediate in the conversion of saturated hydrocarbons into ketones. This second intermediate is probably an FeIII alkoxide. © 1990.

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页码：2817 / 2820

页数：4

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