PREPARATION AND CHARACTERIZATION OF [MN11O10CL2(OAC)11(BPY)2(MECN)2(H2O)2](CLO4)2.8MECN, A MIXED-VALENCE MANGANESE(III/IV) AGGREGATE WITH RARE UNDECANUCLEARITY (BPY = 2,2'-BIPYRIDYL)

被引：29

作者：

PERLEPES, SP

HUFFMAN, JC

CHRISTOU, G

机构：

[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

[2] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 23期

关键词：

D O I：

10.1039/c39910001657

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [Mn4O2(OAc)7(bpy)2](ClO4).3H2O (bpy = 2,2'-bipyridyl) 1 with Me3SiCl in MeCN leads to a disproportionation and nuclearity change to give [Mn11O10Cl2(OAc)11(bpy)2(MeCN)2(H2O)2](ClO4)2.8MeCN 2; the crystal structure shows the core of this aggregate to comprise two [Mn4O3Cl]6+ cubane units 'bridged' by a nearly linear [Mn3O4]+ moiety.

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页码：1657 / 1659

页数：3

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