REACTION OF [RU-5(MU-CCH2)(MU-3-SME)2(MU-PPH2)2(CO)10] WITH [FE-2(CO)9] - FORMATION OF A NOVEL MU-4-VINYLIDENE LIGAND

被引：12

作者：

ADAMS, CJ ^{[1
]}

BRUCE, MI ^{[1
]}

SKELTON, BW ^{[1
]}

WHITE, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 20期

关键词：

D O I：

10.1039/dt9920003057

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between [Ru5(mu3-CCH2)(mu3-SMe)2(mu-PPh2)2(CO)10] and [Fe2(CO)9] afforded the electron-rich mixed-metal cluster [FeRu5(mu4-CCH2)(mu3-SMe)(mu-SMe)(mu-PPh2)2(CO)13], with a symmetrical mu4-vinylidene ligand; the metal core consists of an Ru5 bow-tie, the central and two wing-tip atoms of which are attached to the Fe atom.

引用

页码：3057 / 3058

页数：2

共 7 条

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