PHOTOINDUCED ELECTRON-TRANSFER REACTION OF DIFLUORODIIODOMETHANE WITH AZA-AROMATIC COMPOUNDS AND ENAMINES

被引：35

作者：

CHEN, QY

LI, ZT

机构：

[1] Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 06期

关键词：

D O I：

10.1039/p19930000645

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Irradiation of difluorodiiodomethane 1 with pyrroles. indole and imidazoles in dimethylformamide gives the corresponding trifluoromethylated products, whereas irradiation with enamines results in 2-trifluoromethyl ketones. A photoinduced electron-transfer mechanism is proposed.

引用

页码：645 / 648

页数：4

共 32 条

[1] MICHAELIS-ARBUZOV PREPARATION OF HALO-F-METHYLPHOSPHONATES
BURTON, DJ
FLYNN, RM
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1977, 10 (04) : 329 - 332
[2] A REMARKABLY SIMPLE PREPARATION OF (TRIFLUOROMETHYL)CADMIUM AND (TRIFLUOROMETHYL) ZINC REAGENTS DIRECTLY FROM DIFLUORODIHALOMETHANES
BURTON, DJ
WIEMERS, DM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (17) : 5014 - 5015
[3] SYNTHESIS OF BROMODIFLUOROMETHYL PHENYL SULFIDE, SULFOXIDE AND SULFONE
BURTON, DJ
WIEMERS, DM
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1981, 18 (4-6) : 573 - 582
[4] BURTON DJ, 1977, FLUORINE CHEM REV, V8, P119
[5] CONDENSATION OF PERFLUOROALKYL IODIDES WITH UNSATURATED NITROGEN-COMPOUNDS
CANTACUZENE, D
WAKSELMAN, C
DORME, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (12): : 1365 - 1371
[6] CHEETHAM NF, 1965, J CHEM SOC CHEM COMM, P418
[7] STUDIES ON FLUOROALKYLATION AND FLUOROALKOXYLATION .10. ELECTRON-TRANSFER INDUCED REACTIONS OF PERFLUOROALKYL IODIDES AND THE DIALKYL MALONATE ANION AND BETA-FRAGMENTATION OF THE HALOTETRAFLUOROETHYL RADICAL
CHEN, QY
QIU, ZM
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1986, 31 (03) : 301 - 317
[8] PHOTOINDUCED ELECTRON-TRANSFER PERFLUOROALKYLATION OF AMINOPYRIDINES WITH PERFLUOROALKYL IODIDES
CHEN, QY
LI, ZT
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1992, (11): : 1443 - 1445
[9] STUDIES ON FLUOROALKYLATION AND FLUOROALKOXYLATION .16. REACTIONS OF FLUOROALKYL IODIDES WITH SOME NUCLEOPHILES BY SRN1 MECHANISM
CHEN, QY
QIU, ZM
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1987, 35 (02) : 343 - 357
[10] CHEN QY, 1987, J CHEM SOC CHEM COMM, P364

← 1 2 3 4 →