A SIMPLE, GENERAL AND STEREOSELECTIVE SYNTHESIS OF 1-(DIALKOXYBORYL)-1,3-DIENES

被引:25
作者
MAZAL, C [1 ]
VAULTIER, M [1 ]
机构
[1] UNIV RENNES 1,CNRS,RECH PHYSICOCHIM STRUCT GRP,F-35042 RENNES,FRANCE
关键词
D O I
10.1016/S0040-4039(00)76836-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A simple, general and highly stereoselective synthesis of 1-dialkoxylboryl-1,3-dienes that involves a palladium (0) catalyzed cross-coupling reaction of the boronic ester 4 derived from (E)-2-bromoethenylboronic acid and 2,2-dimethyl-1,3-propanediol with various alkenylzinc chlorides is described.
引用
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页码:3089 / 3090
页数:2
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