EFFECT OF STRUCTURE-MAKING AND -BREAKING SOLUTES ON TEMPERATURE OF MAXIMUM DENSITY OF WATER

被引：59

作者：

DARNELL, AJ

GREYSON, J

机构：

[1] Atomics International Division, North American Rockwell Corporation, Canoga Park

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1968年 / 72卷 / 08期

关键词：

D O I：

10.1021/j100854a060

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Measurements have been made of the displacement of the temperature of maximum density (Tm) of water resulting from the solution of several quaternary ammonium halides and the iodine-iodide ion complex. The results indicate that the water structure-promoting characteristics of the species ordinarily found at room temperature are not manifested in the neighborhood of Tm. The results are attributed to ion-size effects which become important at temperatures approaching Tm because of the enhanced structure of the solvent.

引用

页码：3021 / &

共 14 条

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