ONE-POT ANNULATION TO TRICYCLO[5.3.1.0/3,8]UNDECANE-2,6-DIONES BY SEQUENTIAL 3-FOLD MICHAEL REACTIONS - A FORMAL SYNTHESIS OF (+/-)-SEYCHELLENE

被引：8

作者：

HAGIWARA, H

OKANO, A

UDA, H

机构：

[1] Chemical Research Institute of Non-Aqueous Solutions, Tohoku University, Katahira, Aoba-ku

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 07期

关键词：

D O I：

10.1039/p19900002109

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Lewis acid-assisted triple Michael reactions yield tricyclo[5.3.1.0 3,8]undecane-2,6-dione derivatives from the trimethylsilyl enol ethers of cyclohex-2-enones and divinyl ketone. The application of this reaction allowed a formal synthesis of (±)-seychellene.

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页码：2109 / 2113

页数：5

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