SYNTHESIS AND STRUCTURE OF ORGANOTIN COMPLEXES OF YTTERBIUM

被引：30

作者：

BOCHKAREV, LN

GRACHEV, OV

ZILTSOV, SF

ZAKHAROV, LN

STRUCHKOV, YT

机构：

[1] RUSSIA ACAD SCI,INST ORGANOMET CHEM,GORKI,USSR

[2] AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW,USSR

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 436卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)85062-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of Ph3SnCl, PhSnCl3 and Ph3SnSnPh3 With ytterbium in THF lead to the formation of the complex (Ph3Sn)2Yb(THF), (1) * in high yields. According to X-ray data, tin atoms in complex 1 are covalently bonded with the ytterbium atom. Ionic organotin complex of ytterbium [(Ph3Sn)3Sn]2-[Yb2Cl2(DME)6]2+ (2) was synthesised in 75% yield by the reaction of Ph2SnCl2 with ytterbium. According to X-ray analysis, the compound consists of [(Ph3Sn)3Sn]- anions and dimeric ytterbium cations with mu2-bridged chlorine atoms [GRAPHICS]

引用

页码：299 / 311

页数：13

共 14 条

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