BINDING-PROPERTIES OF P-(PHENYLAZO)CALIXARENES FOR METAL-IONS

被引：24

作者：

NOMURA, E ^{[1
]}

TANIGUCHI, H ^{[1
]}

OTSUJI, Y ^{[1
]}

机构：

[1] UNIV OSAKA PREFECTURE, COLL ENGN, DEPT APPL CHEM, SAKAI, OSAKA 593, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 12期

关键词：

D O I：

10.1246/bcsj.66.3797

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The binding properties of p-(phenylazo)calix[n]arenes (n=6 and n=4) for metal ions have been studied. The calixarenes show a highly selective binding ability toward Ag+, Hg+, and Hg2+. This property can be explained in terms of a metal ion-induced azo/hydrazone tautomerism. The Ag+ ion forms complexes with the azocalixarenes by binding with their hydrazone tautomers.

引用

页码：3797 / 3801

页数：5

共 33 条

[1] MOLECULAR INCLUSION IN FUNCTIONALIZED MACROCYCLES .6. THE CRYSTAL AND MOLECULAR-STRUCTURES OF THE CALIX[4]ARENE FROM PARA-(1,1,3,3-TETRAMETHYLBUTYL)PHENOL AND ITS 1-1 COMPLEX WITH TOLUENE [J].

ANDREETTI, GD ;

POCHINI, A ;

UNGARO, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1983, (11) :1773-1779

[2] CRYSTAL AND MOLECULAR-STRUCTURE OF CYCLO(QUATER[(5-TERT-BUTYL-2-HYDROXY-1,3-PHENYLENE)METHYLENE]) TOLUENE (1-1) CLATHRATE [J].

ANDREETTI, GD ;

UNGARO, R ;

POCHINI, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (22) :1005-1007

[3] On the knowledge of m-Xylenol. [J].

Auwers, K ;

Markovits, T .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1908, 41 :2332-2340

[4]

BOHMER V, 1990, J ORG CHEM, V55, P2569

[5] ALTERNATIVE METHODS OF MODIFYING THE CALIXARENE CONFORMATION - THE SYNTHESIS AND MOLECULAR-STRUCTURES OF TERT-BUTYLCALIX[4]ARENE METHYL-ETHER COMPLEXED WITH ALUMINUM ALKYL SPECIES [J].

BOTT, SG ;

COLEMAN, AW ;

ATWOOD, JL .

JOURNAL OF INCLUSION PHENOMENA, 1987, 5 (06) :747-758

[6] PREPARATION AND STRUCTURE OF THE 1ST COMPLEX OF AN EARLY TRANSITION-METAL AND A CALIXARENE, CALIX[6]ARENE[TICL2(MU-O)TICL3]2 [J].

BOTT, SG ;

COLEMAN, AW ;

ATWOOD, JL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (08) :610-611

[7] NEW METAL CATION-SELECTIVE IONOPHORES DERIVED FROM CALIXARENES - THEIR SYNTHESES AND ION-BINDING PROPERTIES [J].

CHANG, SK ;

CHO, I .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (02) :211-214

[8]

Gutsche C. D., 1989, MONOGRAPHS SUPRAMOLE

[9] CALIXARENES .23. THE COMPLEXATION AND CATALYTIC PROPERTIES OF WATER-SOLUBLE CALIXARENES [J].

GUTSCHE, CD ;

ALAM, I .

TETRAHEDRON, 1988, 44 (15) :4689-4694

[10] CALIXARENES .22. SYNTHESIS, PROPERTIES, AND METAL COMPLEXATION OF AMINOCALIXARENES [J].

GUTSCHE, CD ;

NAM, KC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (18) :6153-6162

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