STUDY OF INTERACTION OF OLEFINS WITH PALLADIUM BY COMPETITIVE REACTION METHOD

被引：17

作者：

MOROOKA, Y

KITAMURA, T

OZAKI, A

机构：

[1] Research Laboratory of Resources Utilization, Tokyo Institute of Technology, Meguro-ku, Tokyo, Ohokayama

来源：

JOURNAL OF CATALYSIS | 1969年 / 13卷 / 01期

关键词：

D O I：

10.1016/0021-9517(69)90369-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The interactions of olefins with palladium catalyst during their catalytic oxidation were studied by means of a competitive reaction method. Relative values of adsorption constants for C4 and C5 olefins have been determined and are compared with the corresponding stability constants of various π-complexes of olefins. The trend in the adsorption constants for isomeric olefins was found to be similar to the stability constants of the corresponding π-complexes with silver nitrate, molecular iodine, palladium chloride, and acac-Rh(C2H4). © 1969.

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页码：53 / &

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