UNIQUE REACTIVITY OF HETERODINUCLEAR PENTACARBONYL(FULVALENE)MOLYBDENUMRUTHENIUM WITH ALKYNES - FLUXIONALITY, REARRANGEMENTS, STRUCTURES, AND 1ST REVERSIBLE CONVERSION OF A SIDE-ON - TO A SEMI-BRIDGING ALKENYLIDENE LIGAND

被引：22

作者：

BOESE, R

HUFFMAN, MA

VOLLHARDT, KPC

机构：

[1] UNIV CALIF BERKELEY,LAWRENCE BERKELEY LAB,DIV CHEM SCI,BERKELEY,CA 94720

[2] UNIV ESSEN GESAMTHSCH,INST ANORGAN CHEM,W-4300 ESSEN 1,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 11期

关键词：

D O I：

10.1002/anie.199114631

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acting as as two- and four-electron donors alkynes react with the heteronuclear fulvalene complex 1. Terminally bound alkyne ligands rearrange to alkenylidene ligands; in the course of the reaction an equilibrium between the side-on and semibridging coordination (2 reversible 3) can be observed. (2: R1 = C6H5, R2 = H).

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页码：1463 / 1465

页数：3

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