CONFIGURATION OF THE 3,12 DOUBLE-BOND OF ROQUEFORTINE

被引：36

作者：

SCOTT, PM ^{[1
]}

POLONSKY, J ^{[1
]}

MERRIEN, MA ^{[1
]}

机构：

[1] CNRS,INST CHIM SUBST NAT,F-91190 GIF SUR YVETTE,FRANCE

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1979年 / 27卷 / 01期

关键词：

D O I：

10.1021/jf60221a052

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

The E configuration of the 3, 12 double bond of roquefortine, a metabolite of the commercially important fungus Penicillium roqueforti, was established by comparison of its spectral properties with those of a photoisomer. The structure (E)-3-(H-imidazol-4-ylmethylene)-6-(H-indol-3-ylmethyl)-2, 5-piperazinedione is proposed for the major product of an acid-catalyzed de-isoprenylation reaction of roquefortine. © 1979, American Chemical Society. All rights reserved.

引用

页码：201 / 202

页数：2

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