KINETICS OF THE THERMAL-DECOMPOSITION OF BIS-PENTAFLUOROSULFUR TRIOXIDE (SF5O3SF5) IN THE PRESENCE OF CARBON-MONOXIDE

被引：16

作者：

CZARNOWSKI, J

SCHUMACHER, HJ

机构：

[1] Instituto de Investigaciones Fisicoquimicas Teoricas y Aplicadas, La Plata

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1979年 / 11卷 / 10期

关键词：

D O I：

10.1002/kin.550111007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The thermal decomposition of SF5O3SF5 in the presence of CO has been investigated between ‐9.8°C and + 9.9°C. Besides traces of S2F10, equimolecular amounts of SF5O2SF5 and CO2 are formed. (Formula Presented.) The reaction is homogeneous. Its rate is proportional to the pressure of the trioxide and in dependent of the total pressure, the pressure of inert gases and of carbon monoxide: (Formula Presented.) where k = k1∞ = 1016.32±0.40 exp(−25,300 ± 500 cal)/RT sec−1. Consequently, (Formula Presented.) In the presence of oxygen a sensitized CO2 formation is observed. A mechanism is given which explains the experimental results. Copyright © 1979 John Wiley & Sons, Inc.

引用

页码：1089 / 1096

页数：8

共 5 条

[1] BENSON SW, 1969, INT J CHEM KINET, V1, P451
[2] DATA ON FORMATION AND DECOMPOSITION OF BIS (PENTAFLUOROSULFUR) TRIOXIDE, BIS (PENTAFLUOROSULFUR) DIOXIDE, BIS (PENTAFLUOROSULFUR) MONOXIDE AND OF RADICALS SF5O2 AND SF5O - REVIEW OF EARLIER KINETIC INVESTIGATIONS
CZARNOWSKI, J
SCHUMACHER, HJ
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1978, 12 (06) : 497 - 503
[3] KINETICS OF THERMAL-DECOMPOSITION OF BIS-PENTAFLUORINE SULFUR PEROXIDE IN PRESENCE OF CARBON-MONOXIDE
CZARNOWSKI, J
SCHUMACHER, HJ
[J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1978, 10 (01) : 111 - 116
[4] CZARNOWSKI J, UNPUBLISHED
[5] CZARNOWSKI J, 1977, REV LATINOAM QUIM, V8, P143

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