INFRARED STUDY OF H+(H2O)N-BETA-'' ALUMINA

被引：37

作者：

COLOMBAN, P ^{[1
]}

NOVAK, A ^{[1
]}

机构：

[1] CNRS,SPECTROCHIM INFRAROUGE & RAMAN LAB,F-94320 THIAIS,FRANCE

来源：

SOLID STATE COMMUNICATIONS | 1979年 / 32卷 / 06期

关键词：

D O I：

10.1016/0038-1098(79)91098-6

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Infrared spectra of H+(H2O)nβ″ alumina show than the dehydrated samples contain H3O+ ions as dominant species while the hydrated ones consists mainly of H3O+ and H5O+2 entities. Oxonium ions can occupy many different positions more or less distant form the ideal prismatic sites. This structural disorder in the conductivity plane is believed to be the main factor responsible for the high conductivity of the material. © 1979.

引用

页码：467 / 471

页数：5

共 13 条

[1] COLOMBAN P, 1978, NOUV J CHIM, V2, P21
[2] VIBRATIONAL-SPECTRA AND STRUCTURE OF H+(H2O)NBETA-ALUMINA
COLOMBAN, P
LUCAZEAU, G
MERCIER, R
NOVAK, A
[J]. JOURNAL OF CHEMICAL PHYSICS, 1977, 67 (11) : 5244 - 5251
[3] COLOMBAN P, 1978, 2ND INT M SOL EL ST
[4] DESBAT B, 1975, SPECTROCHIM ACTA A, V31, P1100
[5] HYDRONIUM BETA ALUMINA - FAST PROTON CONDUCTOR
FARRINGTON, GC
BRIANT, JL
[J]. MATERIALS RESEARCH BULLETIN, 1978, 13 (08) : 763 - 773
[6] FARRINGTON GC, 1978, 2ND INT M SOL EL ST
[7] JENSEN J, 1978, MAT SCI LETT, V13, P909
[8] KAHN A, UNPUBLISHED
[9] EFFECT OF HYDROGEN-BONDING ON NH STRETCHING RAMAN BAND OF PYRROLE
LAUTIE, A
NOVAK, A
[J]. JOURNAL OF CHEMICAL PHYSICS, 1972, 56 (05) : 2479 - &
[10] Novak A., 1974, STRUCT BOND, V18, P177, DOI [10.1007/BFb0116438, DOI 10.1007/BFB0116438]

← 1 2 →