UPPER LIMIT FOR THE RATE CONSTANT OF THE BIMOLECULAR REACTION CH3+O2-]OH+H2CO AT 368-K

被引：15

作者：

KLAIS, O

ANDERSON, PC

LAUFER, AH

KURYLO, MJ

机构：

[1] NBS,DIV CHEM KINET,WASHINGTON,DC 20234

[2] NBS,NATL MEASUREMENT LAB,WASHINGTON,DC 20234

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 66卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)80349-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An upper limit for the rate constant of the bimolecular reaction CH3 + O2 - OH + H2CO at 368 K has been measured by monitoring OH using the flash photolysis-resonance fluorescence technique. Careful modeling of the system in conjunction with statistical analysis indicates upper limit of k ≤ 3 x 10-16cm3 molec-1 s-1. The rate constant of the reaction of OH with azomethane has also been measured. © 1979.

引用

页码：598 / 601

页数：4

共 14 条

[1] REACTIONS OF METHYL RADICALS OF IMPORTANCE IN COMBUSTION SYSTEMS [J].