CHEMICALLY ACTIVATED METHYLCYCLOBUTANE FROM THE 337.1 NM PHOTOLYSIS OF KETENE IN THE PRESENCE OF CYCLOBUTANE - DEPENDENCE OF S-D ON EXTENT OF PHOTOLYSIS

被引:9
作者
KOLLN, WS
JOHNSON, M
PEEBLES, DE
SIMONS, JW
机构
[1] Department of Chemistry, New Mexico State University, Las Cruces
基金
美国国家科学基金会;
关键词
D O I
10.1016/0009-2614(79)80132-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The 3371 A photolysis of ketene/cyclobutane/oxygen mixtures gave stabilization/decomposition ratios for chemically activated methylcyclobutane that varied with the extent of photolysis. Experiments designed to circumvent this complication gave a 10 ± 2 kcal/mole collisional deactivation step size for cyclobutane. © 1979.
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页码:85 / 88
页数:4
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