NEW ROUTE TO (-)-FRONTALIN AND (-)-MALYNGOLIDE VIA EPOXYKETONE REARRANGEMENT

被引：32

作者：

ASAOKA, M

HAYASHIBE, S

SONODA, S

TAKEI, H

机构：

[1] Department of Life Chemistry, Tokyo Institute of Technology, Midoriku, Yokohama

来源：

TETRAHEDRON | 1991年 / 47卷 / 34期

关键词：

(-)-FRONTALINE; (-)-MALYNGOLIDE; RING CONTRACTION; EPOXYKETONE; REARRANGEMENT;

D O I：

10.1016/S0040-4020(01)96151-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis of the title compounds by utilizing BF3.Et2O catalyzed ring contraction of 2,3-epoxycyclohexanones leading to 2-alkyl-2-formylcyclopentanones is described.

引用

页码：6967 / 6974

页数：8

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