VIBRATIONAL-SPECTRA OF ACETYL ISOCYANATE AND MONOCHLOROACETYL, DICHLOROACETYL AND TRICHLOROACETYL ISOCYANATES

被引：14

作者：

BALFOUR, WJ ^{[1
]}

FOUGERE, SG ^{[1
]}

KLAPSTEIN, D ^{[1
]}

NAU, WM ^{[1
]}

机构：

[1] ST FRANCIS XAVIER UNIV,DEPT CHEM,ANTIGONISH B2G 1C0,NS,CANADA

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1993年 / 299卷

关键词：

D O I：

10.1016/0022-2860(93)80280-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The gas-phase infrared and liquid-phase Raman spectra of R-CO-NCO, where R = CH3, CH2Cl, CHCl2 and CCl3, have been recorded. For each molecule an assignment of the observed bands has been proposed in terms of the two planar conformers derived from rotation about the C-N bond. The observations indicate that the cisoid conformation is the preferred one in the gas phase while substantial amounts of both cisoid and transoid conformers are present in the liquid.

引用

页码：21 / 28

页数：8

共 18 条

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