REMARKABLE RATE ENHANCEMENT IN CO INSERTION INTO PD-C BOND BY GENERATING CATIONIC ORGANOPALLADIUM COMPLEXES [PDR(S)L(2)]+BF4- (R=ALKYL GROUP, S=ACETONE, L=PHOSPHINE-LIGANDS) FROM NEUTRAL MONOORGANOPALLADIUM COMPLEXES [PDR(X)L(2)] (X=HALIDE)

被引：21

作者：

KAYAKI, Y ^{[1
]}

KAWATAKA, F ^{[1
]}

SHIMIZU, I ^{[1
]}

YAMAMOTO, A ^{[1
]}

机构：

[1] WASEDA UNIV, SCH SCI & ENGN, DEPT APPL CHEM, SHINJUKU KU, TOKYO 169, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 11期

关键词：

D O I：

10.1246/cl.1994.2171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Removal of the halide ligand X in PdR(X)L(2) with AgBF4 generates solvent-coordinated cationic organopalladium complexes [PdR(s)L(2)]BF4 which show much higher reactivities for CO insertion than the parent neutral complexes.

引用

页码：2171 / 2174

页数：4

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