PIGMENTS OF FUNGI .32. SYNTHESIS OF (S)-(-)-AUSTROCORTICIN AND (S)-(+)-DERMOLACTONE - ABSOLUTE STEREOCHEMISTRY OF THE NATURAL-PRODUCTS

被引：8

作者：

COTTERILL, AS ^{[1
]}

GILL, M ^{[1
]}

机构：

[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(00)93405-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The anthraquinones (S)-(-)-austrocorticin (9) and (S)-(+)-dermolactone (2) are synthesised using the chiral dienes 6a and 6b, respectively; comparison with these synthetic compounds establishes that natural austrocorticin has the (R) absolute configuration while dermolactone occurs naturally as a mixture of enantiomers in which the (S) isomer

引用

页码：3155 / 3158

页数：4

共 10 条

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