POLYMERS AND POLYMER METAL-COMPLEXES CONTAINING PENDENT 2,2'-6',2''-TERPYRIDINYL LIGANDS

被引：52

作者：

POTTS, KT

USIFER, DA

机构：

[1] Rensselaer Polytechnic Inst, Troy,, NY, USA, Rensselaer Polytechnic Inst, Troy, NY, USA

来源：

MACROMOLECULES | 1988年 / 21卷 / 07期

关键词：

MONOMERS; -; Polymerization; STYRENE; Processing;

D O I：

10.1021/ma00185a016

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Homopolymers and styrene copolymers derived from 4'-vinyl-2,2'; 6',2 double prime -terpyridinyl were prepared in chlorobenzene at 60 degree C by using azobis(isobutyronitrile) (AIBN) initiation, and monomer reactivity ratios were determined for the styrene copolymers. These polymeric systems containing pendent terpyridinyl ligands readily formed complexes with Co, Cu, and Zn cations. Although vinylterpyridinyl cobalt and ruthenium complex monomers did not undergo homopolymerization with AIBN initiation, they readily formed styrene copolymers under these polymerization conditions. Removal of the metal ions from these polymer-metal complexes occurred readily on washing the complex with acid.

引用

页码：1985 / 1991

页数：7

共 29 条

[1] RECTIFYING INTERFACES USING 2-LAYER FILMS OF ELECTROCHEMICALLY POLYMERIZED VINYLPYRIDINE AND VINYLBIPYRIDINE COMPLEXES OF RUTHENIUM AND IRON ON ELECTRODES [J].