INHIBITION OF THE ADSORPTION OF CYCLOHEXENE OVER A PD/SEPIOLITE CATALYST BY ACRYLAMIDE

被引：10

作者：

ARAMENDIA, MA

BORAU, V

JIMENEZ, C

MARINAS, JM

SEMPERE, ME

URBANO, FJ

机构：

[1] Department of Organic Chemistry, University of Córdoba, Córdoba

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1990年 / 41卷 / 01期

关键词：

D O I：

10.1007/BF02075495

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Cyclohexene acts as a powerful hydrogen donor over supported Pd catalysts. On the basis of the theory of competitive hydrogenations, this paper aims at accounting for the fact that acrylamide cannot be reduced by hydrogen transfer using cyclohexene as donor, whereas methacrylamide can. © 1990 Akadémiai Kiadó.

引用

页码：141 / 146

页数：6

共 11 条

[1]

Brieger G., Nestrick T., Chem. Rev., 74, (1974)

[2]

Johnstone R.A.W., Wilby A.H., Entwistle I.D., Chem. Rev., 85, (1985)

[3]

Aramendia M.A., Borau V., Jimenez C., Marinas J.M., Sempere M.E., Urbano P., Appl. Catal., 43, (1988)

[4]

Alba A., Aramendia M.A., Borau V., Garcia-Raso A., Jimenez C., Marinas J.M., Can. J. Chem., 62, (1988)

[5]

Aramendia M.A., Borau V., Jimenez C., Marinas J.M., Sempere M.E., Use of Pd/sepiolite systems as hydrogenation catalysts. II. Hydrogenolysis ofN-blocked amino acids and dipeptides by hydrogen transfer, Canadian Journal of Chemistry, 65, (1987)

[6]

Aramendia M.A., Borau V., Gomez J., Jimenez C., Marinas J.M., Appl. Catal., 10, (1984)

[7]

Aramendia M.A., Borau V., Castellano F., Jimenez C., Marinas J.M., React. Kinet. Catal. Lett., 36, (1988)

[8]

Cerveny L., Ruzicka V., Catal. Rev. Sci. Eng., 24, (1982)

[9]

Cabello J.A., Campelo J.M., Garcia A., Luna D., Marinas J.M., J. Catal., 94, (1985)

[10]

Rader C.P., Smith H.A., J. Am. Chem. Soc., 84, (1962)

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