HIGH-PRESSURE STOPPED-FLOW APPARATUS UP TO 3-KBAR

被引：22

作者：

SASAKI, M

AMITA, F

OSUGI, J

机构：

[1] Department of Chemistry, Faculty of Science, Kyoto University

来源：

REVIEW OF SCIENTIFIC INSTRUMENTS | 1979年 / 50卷 / 09期

关键词：

D O I：

10.1063/1.1135993

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

A high-pressure stopped-flow apparatus was constructed which could be operative at hydrostatic pressures up to 3 kbar. Some preparative results on anionic σ-complex formation reactions are presented up to 1.5 kbar between 2,4,6-trinitrobenzene (I) and hydroxide ion and between compound (I) and sulfite ion in water. It was found that this apparatus was sufficient to follow a chemical reaction whose half-life was longer than several milliseconds.

引用

页码：1104 / 1107

页数：4

共 11 条

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