LINEAR 4-ATOMIC MOLECULES IN THE VIBRON MODEL

被引：90

作者：

IACHELLO, F

OSS, S

LEMUS, R

机构：

[1] UNIV TRENTO,DIPARTMENTO FIS,I-38050 TRENT,ITALY

[2] IST NAZL FIS NUCL,GRP COLLEGATO TRENTO,I-38050 TRENT,ITALY

[3] NATL AUTONOMOUS UNIV MEXICO,INST CIENCIAS NUCL,MEXICO CITY 04510,DF,MEXICO

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1991年 / 149卷 / 01期

关键词：

D O I：

10.1016/0022-2852(91)90148-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

We present a general scheme for calculating spectra of linear four-atomic molecules and apply it to the study of acetylene, C2H2, and its isotopic variations, C2D2 and C2HD. Particular emphasis is given to the phenomenon of l-splitting, which plays an important role in four-atomic molecules. We are able to describe all known experimental levels, including stretching and bending, with an average rms of 10 cm-1. © 1991.

引用

页码：132 / 151

页数：20

共 40 条

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ADAMS JE, 1977, J MOL SPECTROSC, V64, P157

[2] ROTATIONAL DISTORTION IN LINEAR MOLECULES ARISING FROM L-TYPE RESONANCE [J].