COBALT(II) SCHIFFS BASE COMPLEX-CATALYZED OXIDATION OF ALCOHOLS WITH DIOXYGEN IN THE PRESENCE OF ETHYL 2-OXOCYCLOPENTANECARBOXYLATE

被引：16

作者：

PUNNIYAMURTHY, T ^{[1
]}

IQBAL, J ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,KANPUR 208016,UTTAR PRADESH,INDIA

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 23期

关键词：

D O I：

10.1016/S0040-4039(00)76726-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cobalt(II) Schiff's base complex 1 catalyses the oxidation of primary and secondary alcohols to aldehydes and ketones respectively, in the presence of dioxygen and ethyl 2-ozocyclopentanecarboxylate 2 at 60-70 degrees C.

引用

页码：4007 / 4010

页数：4

共 15 条

[1] EPOXIDATION OF CYCLIC ALKENES BY BIS(ACETONITRILE)CHLORONITROPALLADIUM(II) - ON THE ROLE OF HETEROMETALLACYCLOPENTANES AND BETA-HYDROGEN ELIMINATION IN THE CATALYTIC-OXIDATION OF ALKENES [J].

ANDREWS, MA ;

CHENG, CWF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (15) :4268-4270

[2] COBALT(II) CATALYZED REACTION OF ALKENES WITH ALIPHATIC-ALDEHYDES AND MOLECULAR-OXYGEN - SCOPE AND MECHANISM [J].

BHATIA, S ;

PUNNIYAMURTHY, T ;

BHATIA, B ;

IQBAL, J .

TETRAHEDRON, 1993, 49 (27) :6101-6122

[3] MONOMERIC OXYGEN ADDUCTS OF N,N'-ETHYLENEBIS(ACETYLACETONIMINATO)LIGANDCOBALT(II) . PREPARATION AND PROPERTIES [J].

CRUMBLISS, AL ;

BASOLO, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (01) :55-+

[4]

DIAMOND SE, 1982, J AM CHEM SOC, V104, P4268

[5] EPOXIDATION REACTIONS CATALYZED BY IRON PORPHYRINS - OXYGEN-TRANSFER FROM IODOSYLBENZENE [J].

GROVES, JT ;

NEMO, TE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (18) :5786-5791

[6] MECHANISTICS STUDIES ON THE COBALT(II) SCHIFF-BASE CATALYZED OXIDATION OF OLEFINS BY O-2 [J].

HAMILTON, DE ;

DRAGO, RS ;

ZOMBECK, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (02) :374-379

[7]

KANEMOTO S, 1984, TETRAHEDRON LETT, V25, P3317, DOI 10.1016/S0040-4039(01)81373-3

[8]

MIMOUN H, 1987, COMPEREHENSIVE COORD, V6

[9] COBALT(II) CATALYZED EPOXIDATION OF UNFUNCTIONALIZED ALKENES WITH IN-SITU GENERATED HYDROPEROXIDE FROM METHYL-2-OXOCYCLOPENTANE CARBOXYLATE AND MOLECULAR-OXYGEN [J].

PUNNIYAMURTHY, T ;

BHATIA, B ;

IQBAL, J .

TETRAHEDRON LETTERS, 1993, 34 (29) :4657-4658

[10]

Sheldon R. A., 1981, METAL CATALYZED OXID

← 1 2 →