STEREOCHEMISTRY OF ALTERNATING POLYOL CHAINS - C-13 NMR ANALYSIS OF 1,3-DIOL ACETONIDES

被引：527

作者：

RYCHNOVSKY, SD

SKALITZKY, DJ

机构：

[1] Department of Chemistry, University of Minnesota, Minneapolis

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 07期

关键词：

D O I：

10.1016/S0040-4039(00)94399-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acetonides of syn and anti 1,3-diols (4,6-dialkyl-2,2-dimethyl-1,3-dioxanes) can be easily and unambiguously distinguished by 13C NMR. The stereochemistry of many alternating (1,3,5...) polyol chains can be determined by preparation and 13C NMR analysis of two frame-shifted polyacetonide derivatives. © 1990.

引用

页码：945 / 948

页数：4

共 19 条

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