PAIR DISTRIBUTION FUNCTION FOR FLUID HARD SPHERES

被引：34

作者：

WATTS, RO

HENDERSON, D

机构：

[1] Department of Applied Mathematics, University of Waterloo, Waterloo, ON

[2] Department of Physics, University of Waterloo, Waterloo, ON

来源：

MOLECULAR PHYSICS | 1969年 / 16卷 / 03期

关键词：

D O I：

10.1080/00268976900100281

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The pair distribution function of a system of fluid hard spheres is calculated by means of a simple generalization of the Percus-Yevick theory. A relation between the pair distribution function and the direct correlation function which leads to self-consistent results from the pressure and compressibility equations of state and which is similar, but not identical, to a proposal of Rowlinson, is postulated. This relation leads to an excellent equation of state for fluid hard spheres. Furthermore, in contrast to previous generalizations of the Percus-Yevick theory, this approach makes use only of the results of the Percus-Yevick theory and does not require the solution of a new integral equation. © 1969 Taylor and Francis Group, LLC.

引用

页码：217 / +

页数：1

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