DIALKYLTIN DICHLORIDE COMPLEXES OF 4-PICOLINE

被引：6

作者：

HENDRICKER, DG

机构：

[1] Clippinger Laboratories, Department of Chemistry Ohio University, Athens

来源：

INORGANIC & NUCLEAR CHEMISTRY LETTERS | 1969年 / 5卷 / 02期

关键词：

D O I：

10.1016/0020-1650(69)80181-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Use of the magnitude of spin-spin coupling to infer the geometry of octahedral diakyltin dichloride complexes with 1,8-naphthyridine(1), pyridine N-oxide (2) and dimethyl sulfoxide (3) is well documented. The coupling constants observed for similar complexes wherein 4-picoline is the ligand suggest a trans alkyl configuration. Similarity of the infrared spectra with analogous 1,10-phenanthroline and 2,2′-bipyridine complexes support a cis arrangement for both the 4-picoline and chlorine groups. (4,5). © 1969.

引用

页码：115 / +

页数：1

共 10 条

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[10] VERDONCK L, 1965, BER BUNSEN PHYS CHEM, V69, P479

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