BETA-LACTOGLOBULIN DIRECTED PHOTOISOMERIZATION OF RETINAL AND RELATED-COMPOUNDS

被引：8

作者：

LI, XY ^{[1
]}

ASATO, AE ^{[1
]}

LIU, RSH ^{[1
]}

机构：

[1] UNIV HAWAII,DEPT CHEM,HONOLULU,HI 96822

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(00)97747-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 11-cis enriched photostationary state mixture of retinal trapped in BLG, a water soluble protein, is similar to that of retinal in heptanol. The results, along with those of the lower homologs, are consistent with a model involving specific protein interaction with the cyclohexenyl portion of the substrate and remote protonation of the aldehyde carbonyl group. © 1990.

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页码：4841 / 4844

页数：4

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