RECOMBINATION OF GEMINATE SPECIES IN THE PRESENCE OF A SCAVENGER

被引：74

作者：

TACHIYA, M

机构：

[1] Basic Research Division, National Chemical Laboratory for Industry, Shibuya-ku, Tokyo, Honmachi

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 01期

关键词：

D O I：

10.1063/1.437238

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present a general method for calculating the recombination probability of geminate radicals or ions in the presence of a scavenger. By use of this method the recombination probabilities of geminate radicals in one-, two-, and three-dimensional spaces are analytically calculated as a function of scavenger concentration. The so-called square-root law holds in one- and three-dimensional spaces, but not in a two- dimensional space. The present method is also applied to the recombination probability of geminate ions. The recombination probability of geminate ions in the presence of both a scavenger and an external electric field has been rigorously derived for the first time. © 1979 American Institute of Physics.

引用

页码：238 / 241

页数：4

共 6 条

[1] APPLICATION OF SMOLUCHOWSKI EQUATION TO ELECTRON SCAVENGING IN DIELECTRIC LIQUIDS - NUMERICAL EVALUATION OF SCAVENGING PROBABILITY FOR A GIVEN INITIAL SEPARATION OF AN ION-PAIR [J].