HALOALKYL COMPLEXES OF TRANSITION-METALS - PREPARATION AND CHARACTERIZATION OF (DICHLOROMETHYL)COBALT(III) DERIVATIVES

被引：11

作者：

ALBERTIN, G

ANTONIUTTI, S

BORDIGNON, E

机构：

[1] Dipartimento di Chimica dell’Università di Venezia, Dorsoduro, S. Marta 2137

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 08期

关键词：

D O I：

10.1021/om00158a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dichloromethyl complexes of the type [Co-(CHCl2)(CNR)nP5-n](PF6)2 [n = 2, 3; R = 4-CH3C6H4, 4-CH3OC6H4 4-ClC6H4; P = PhP(OEt)2 were prepared by allowing the compounds [Co(CNR)nP5-n]PF6 to react at -80 °C with aryldiazonlum cations in CH2Cl2. Their characterization by infrared and1H,13C{1H}, and variable-temperature31P{1H} NMR spectroscopy is reported. Some studies on reactions with electrophiles and nucleophiles are also described. © 1990, American Chemical Society. All rights reserved.

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页码：2177 / 2179

页数：3

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