SYNTHESIS, STRUCTURE AND ELECTROCHEMISTRY OF [PD([9]ANENS2)2]-[BF4]2 ([9]ANENS2 = 1,4-DITHIA-7-AZACYCLONONANE)

被引：32

作者：

BLAKE, AJ ^{[1
]}

CROFTS, RD ^{[1
]}

DEGROOT, B ^{[1
]}

SCHRODER, M ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 03期

关键词：

D O I：

10.1039/dt9930000485

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The centrosymmetric purple-blue complex [Pd([9]aneNS2)2][BF4]2 ([9]aneNS2 = 1,4-dithia-7-azacyclononane) shows a primary N2S2 co-ordination, Pd-N(1) 2.081(9), Pd-S(7) 2.322(3) angstrom, with long-range interactions to the two remaining S donors, Pd ... S(4) 3.011(3) angstrom; [Pd([9]aneNS2)2]2+ shows two one-electron oxidations at 1E1/2 = +0.43 V and 2E1/2 = +0.84 V vs. ferrocene-ferrocenium assigned to Pd(II)-Pd(III) and Pd(III)-Pd(IV) couples respectively.

引用

页码：485 / 486

页数：2

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