A NEW MECHANISM FOR THE PHOTOCLEAVAGE OF MONOTHIOIMIDES

被引：5

作者：

FU, TY ^{[1
]}

SCHEFFER, JR ^{[1
]}

TROTTER, J ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1Z1,BC,CANADA

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 20期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0040-4039(00)76873-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Based on solid state structure-reactivity correlation studies and on deuterium labeling experiments, it is concluded that the photochemical formation of thiobenzanilides 2a-d from monothioimides 1a-d does not involve initial gamma-hydrogen atom abstraction as originally suggested in the literature. Alternative mechanistic possibilities are presented and discussed.

引用

页码：3235 / 3238

页数：4

共 8 条

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