MOLECULAR AXIS ORIENTATION BY THE BRUTE FORCE METHOD

被引：24

作者：

LOISON, JC ^{[1
]}

DURAND, A ^{[1
]}

BAZALGETTE, G ^{[1
]}

WHITE, R ^{[1
]}

AUDOUARD, E ^{[1
]}

机构：

[1] CNRS,URA 770,F-31062 TOULOUSE,FRANCE

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 37期

关键词：

D O I：

10.1021/j100037a003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using a strong electric field, it is possible to orient polar molecules in their lowest rotational states. This ''brute force'' technique, introduced by Loesch, is very powerful and has many applications. In this paper, we recall the general theory of the effect, i.e., the properties of the pendular states introduced by Friedrich and Herschbach. We then discuss the effects of hyperfine structure on the orientation process. Finally, we discuss the optimization of an oriented molecular beam of ICl.

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页码：13591 / 13596

页数：6

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