PREPARATION AND PROPERTIES OF PENTAFLUOROSILICATES

被引：59

作者：

CLARK, HC

DIXON, KR

NICOLSON, JG

机构：

[1] Department of Chemistry, University of Western Ontario, London, Ontario

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 03期

关键词：

D O I：

10.1021/ic50073a009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of quaternary ammonium and arsonium pentafluorosilicates is described. It is shown that SiF5 is a relatively weak acceptor, forming an unstable 1:1 ammonia adduct and interacting only weakly with other Lewis bases. The infrared and Raman absorptions due to SiF5 are not inconsistent with a trigonal-bipyramidal geometry. Many spectroscopic similarities with phosphorus pentafluoride are apparent. © 1969, American Chemical Society. All rights reserved.

引用

页码：450 / &

共 13 条

[1] UBER DIE PENTAFLUOROKIESELSAURE
BEHRENDS, K
KIEL, G
[J]. NATURWISSENSCHAFTEN, 1967, 54 (20) : 537 - &
[2] INFRARED SPECTRA OF HEXAHALOGENOMETALLATES(4)
BROWN, DH
DIXON, KR
LIVINGST.CM
NUTTALL, RH
SHARP, DWA
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (01): : 100 - &
[3] AN UNEXPECTED PRODUCT IN REACTION OF PTHCL(P(C2H5)3)2 WITH C2F4 . STRUCTURE OF PTCL(CO)(P(C2H5)3)2+ CATION AND EVIDENCE FOR EXISTENCE OF SIF5-ION
CLARK, HC
CORFIELD, PW
DIXON, KR
IBERS, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (13) : 3360 - &
[4] SIF5-ION AND EVIDENCE FOR EXISTENCE OF GEF5-
CLARK, HC
DIXON, KR
[J]. CHEMICAL COMMUNICATIONS, 1967, (14) : 717 - &
[5] CORFIELD PWR, PRIVATE COMMUNICATIO
[6] MOLECULAR STRUCTURES OF PC14F PC13F2 PC12F3 + PF5 - INFRARED + LOW-TEMPERATURE RAMAN VIBRATIONAL SPECTRA
GRIFFITHS, JE
CARTER, RP
HOLMES, RR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (03) : 863 - &
[7] FORMATION OF PENTAFLUOROSILICATE ANION IN DEHYDROFLUORINATION REACTIONS
HARRIS, JJ
RUDNER, B
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (02) : 515 - &
[8] NUCLEAR MAGNETIC RESONANCE STUDIES ON PENTACOORDINATE SILICON FLUORIDES
KLANBERG, F
MUETTERT.EL
[J]. INORGANIC CHEMISTRY, 1968, 7 (01) : 155 - &
[9] OBSERVATIONS ON THE ADDITION COMPOUND OF SILICON TETRAFLUORIDE AND AMMONIA
MILLER, DB
SISLER, HH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (19) : 4998 - 5000
[10] PENTACOORDINATE SILICON . CRYSTAL STRUCTURE OF DIMETHYLSILYLAMINE PENTAMER
RUDMAN, R
HAMILTON, WC
NOVICK, S
GOLDFARB, TD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (20) : 5157 - &

← 1 2 →