PHOTOELECTRON-SPECTRA OF METHYLGERMANE, TRIFLUORO-METHYLGERMANE AND TRICHLORO-METHYLGERMANE

被引：11

作者：

DRAKE, JE

GLAVINCEVSKI, BM

GORZELSKA, K

机构：

[1] Department of Chemistry, University of Windsor, Windsor

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1979年 / 17卷 / 02期

关键词：

D O I：

10.1016/0368-2048(79)85029-X

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The He(I) and HE(II) photoelectron spectra of the series MeGeX3 (X = H, F, Cl) are reported. Assignments are proposed based on comparison with spectra of similar compounds, particularly those of the Me4Ge and the GeX4 series, and supported by semi-empirical CNDO/2 calculations. There is good correlation between -CNDO/2 and experimental ionisation energies. The expected de-stabilising effect arising from the introduction of a methyl group is particularly marked in the fluoride. © 1979.

引用

页码：73 / 80

页数：8

共 24 条

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