SEPARATION OF SOME PLATINUM METAL 8-HYDROXYQUINOLINATES BY NORMAL PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY

被引：18

作者：

ALIMARIN, IP ^{[1
]}

BASOVA, EM ^{[1
]}

MALYKHIN, AY ^{[1
]}

BOLSHOVA, TA ^{[1
]}

机构：

[1] MV LOMONOSOV STATE UNIV,DEPT CHEM,LENINSKIE GORY,MOSCOW 117234,USSR

来源：

TALANTA | 1990年 / 37卷 / 05期

关键词：

D O I：

10.1016/0039-9140(90)80074-P

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The method of normal phase high-performance liquid chromatography has been applied to the separation and determination of Pd(II), Pt(II), Rh(III), Ir(IV), Ru(III) and Os(IV) as chelates with 8-hydroxyquinoline on a 62 × 2 mm column packed with Silasorb 600 5 μ silica gel by elution with methylene chloride-isopropyl alcohol mixture (97:3 v/v). The detection limits (ng per 5 μl), were Pd 0.3, Pt 1.0, Rh 1.0, Ir 5.0, Ru 1.5, Os 25. The separation time was 12 min at a flow-rate of 0.1 ml/min. © 1990.

引用

页码：485 / 489

页数：5

共 12 条

[1]

Alimarin I P, 1987, J ANAL CHEM-USSR+, V42, P5

[2]

BENEDIKTOV AB, 1984, KOORDINATS KHIM, V10, P1516

[3]

ENGELHARDT H, 1977, HOCHDRUCK FLUSSIGKEI

[4]

FEDOTOVA TD, 1987, IZV SIB OTD AN KHIM, V2, P95

[5]

SCHWEDT G, 1981, CHROMATOGRAPHIC METH

[6]

SOCZEWINSKI E, 1973, CHROMATOGRAPHIA, V6, P269

[7]

Styskin E.L., 1986, PRAKTICHESKAYA VYSOK

[8]

Timerbaev A.R., 1981, ZH ANAL KHIM, V36, P1160

[9]

TIMERBAEV AR, 1982, ZH ANAL KHIM, V37, P1360

[10] PREPARATION AND CHARACTERIZATION OF ALL PLATINUM METAL 8-HYDROXYQUINOLINATES [J].

WENCLAWIAK, B ;

FLEMMING, M .

FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1987, 326 (06) :551-557

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