REACTIONS OF SOME INDOLYL ALCOHOLS AND INDOLYL-OLEFINS WITH ARENESULFONYL AZIDES

被引：5

作者：

BAHADUR, GA ^{[1
]}

BAILEY, AS ^{[1
]}

COSTELLO, G ^{[1
]}

SCOTT, PW ^{[1
]}

机构：

[1] DYSON PERRINS LAB,S PARKS RD,OXFORD OX1 3QY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 09期

关键词：

D O I：

10.1039/p19790002154

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of 1,3-dimethylindol-2-ylmethanols with arenesulphonyl azides afford 2-arenesulphonylamino-1,3-dimethylindoles as the major products, the side chain being lost, whilst hexahydro-5-methylcyclohept[b]indol-6-ol yields 2-arenesulphonylimino-2′-hydroxy-1-methylindoline-3-spirocyclohexanes. From the reaction between 5-methyl-5,8,9,10-tetrahydrocyclohepta[b]indole and p-chlorobenzenesulphonyl azide three products have been isolated and shown to be 2-p-chlorophenylsulphonylimino-1-methylindoline-3-spirocyclohex-2′-ene, 6-p-chlorophenylsulphonylimino-5,6,7,8,9,10-hexahydro-5-methylcyclohepta[b] indole and 2′-p-chlorophenylsulphonylaminomethylene-2-p- chlorophenylsulphonylimino-1-methylindoline-3-spirocyclopentane.

引用

页码：2154 / 2161

页数：8

共 32 条

[1]

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[2]

AHLBRECHT H, COMMUNICATION

[3] REACTIONS OF 5,6,8,9,10,11-HEXAHYDRO-4H-PYRIDO [3,2,1-JK]CARBAZOLE AND OF 5,6,9,10,11,12-HEXAHYDRO-4H,8H-CYCLOHEPTA[4,5]PYRROLO[3,2,1-IJ]QUINOLINE WITH ARENESULFONYL AZIDES [J].