HOMOGENEOUS GAS-PHASE DECYCLIZATION OF TETRALIN AND BENZOCYCLOBUTENE

被引:23
作者
TSANG, W
CUI, JP
机构
[1] Chemical Kinetics Division, National Institute of Standards Technology, Gaithersburg Maryland
关键词
D O I
10.1021/ja00161a001
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tetralin has been decomposed in single pulse shock tube experiments in the temperature range of 1000-1400 K. The initial unimolecular decomposition channels involve the formation of benzocyclobutene and oallyltoluene. Benzocyclobutene decomposes to form styrene. The main products from the hydrogen atom induced decomposition of tetralin are dihydronaphthalene, styrene, indene, and naphthalene. The following rate expressions have been determined: K(tetralin → ethylene + benzocyclobutene) = 3.5 × 1015 exp(-40003/T) s-1, K(tetralin → oallyltoluene) = 1.2 × 1015 exp(-40111/T) s-1, K(benzocyclobutene → styrene) = 1.2 × 1015 exp(-37 396/T) s-1, K(H + tetralin → H2 + 4-phenylbutyl radical) ≥ 0.55 × K(H + mesitylene → oxylene + CH3). Comparisons are made with published results from laser-powdered pyrolysis and shock tube studies, and it is concluded that in both cases initial unimolecular channels are accessed. The temperatures in the laserexperiments are at least as high in the shock tube studies. The rate expressions for tetralin decomposition are compatible with a biradical mechanism and follow the general patterns for related cyclic compounds. © 1990, American Chemical Society. All rights reserved.
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页码:1665 / 1671
页数:7
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