THERMALLY INITIATED FRONTAL POLYMERIZATION OF TRANSITION-METAL NITRATE ACRYLAMIDE COMPLEXES

被引：31

作者：

SAVOSTYANOV, VS

KRITSKAYA, DA

PONOMAREV, AN

POMOGAILO, AD

机构：

[1] RUSSIAN ACAD SCI,INST ENERGY PROBLEMS CHEM PHYS,CHERNOGOLOVKA 142432,RUSSIA

[2] RUSSIAN ACAD SCI,INST CHEM PHYS,CHERNOGOLOVKA 142432,RUSSIA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1994年 / 32卷 / 07期

关键词：

ACRYLAMIDE; COMPLEX; METAL NITRATES; POLYMERIZATION;

D O I：

10.1002/pola.1994.080320701

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The effect of the thermally initiated frontal polymerization of acrylamide complexes of transition metal nitrates such as those of Mn (II), Co (II), Ni (II), and Zn (II) was disclosed. The rate of the polymerization front propagation was found to be 2-9 X 10(-2) cm/c, depending appreciably on sample diameter and density, as well as the presence of radical inhibitor additives. The rate was found to decrease in the series: Co (II) > Ni (II) > Mn (II) > Zn (II). Polymerization was shown to occur directly in the melting region of a complex at 80-100-degrees-C to give three-dimensional polymers. A mechanism of the polymerization being initiated with the products of the partial nitrate group decomposition was proposed. (C) 1994 John Wiley & Sons, Inc.

引用

页码：1201 / 1212

页数：12

共 24 条

[1]

BARVINOK MS, 1978, ZH NEORG KHIM+, V23, P1843

[2]

BARVIPOK MS, 1974, ZH NEORG KHIM+, V19, P571

[3]

BEGISHEV VP, 1984, DOKL AKAD NAUK SSSR, V279, P903

[4]

BELOV BA, 1985, ZH NEORG KHIM+, V30, P2520

[5]

BHADANI SN, 1980, MAKROMOL CHEM, V191, P1089

[6]

BORSIG E, 1968, CHEM ZVESTI, V22, P627

[7]

DAVTYAN SP, 1984, USP KHIM+, V53, P251

[8]

DROVYANKIN AV, 1982, FIZ GOREN VZRYVA, V8, P10

[9]

Ivleva T. P., 1980, FGV, V16, P3

[10] STUDIES ON THERMAL POLYMERIZATION OF ACRYLAMIDE [J].

KISHORE, K ;

SANTHANALAKSHMI, KN .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1981, A16 (05) :941-951

← 1 2 3 →