ELECTROCHEMICAL REACTIONS .V. FORMATION OF CYCLIC GLYCOLS IN REDUCTION OF AROMATIC DIKETONES

被引:19
作者
GOURLEY, RN
GRIMSHAW, J
机构
[1] Department of Chemistry, Queen's University
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 18期
关键词
D O I
10.1039/j39680002388
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The electroreduction of 1,8-diaroylnaphthalenes, 2,2′- diaroylbiphenyls, and αω-diaroyl-propanes, -butanes, and -pentanes with 4-hydroxy- and 4-methoxy-substituents on the aryl group has been examined. Cyclic glycols are formed, together with other products, except in the case of the αω-diaroylpentanes which give linear polymeric glycols. The yields of cis- and trans-glycols are compared.
引用
收藏
页码:2388 / &
相关论文
共 26 条